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Raichu king does not have a crown skin for Minecraft on PC (Java Edition) or Pocket Edition (PE).
PC (Java Edition):
This particular Raichu king does not have a crown skin has thick (4px) arms. It is based on the classic Steve model.
This particular Minecraft Raichu king does not have a crown skin has the following color palette:
Tabasco
Thunderbird
Concrete
Black
Diesel