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I don't know how to make him skin for Minecraft on PC (Java Edition) or Pocket Edition (PE).
PC (Java Edition):
This particular I don't know how to make him skin has thick (4px) arms. It is based on the classic Steve model.
This particular Minecraft I don't know how to make him skin has the following color palette:
Saffron Mango
Buttercup
Casablanca
Sea Buckthorn
White