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Ash Ketchum does not have a hat skin for Minecraft on PC (Java Edition) or Pocket Edition (PE).
PC (Java Edition):
This particular Ash Ketchum does not have a hat skin has thick (4px) arms. It is based on the classic Steve model.
This particular Minecraft Ash Ketchum does not have a hat skin has the following color palette:
Black
White
Jon
Gondola
Cocoa Brown