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I've never seen a skin like that before for Minecraft on PC (Java Edition) or Pocket Edition (PE).
PC (Java Edition):
This particular I've never seen a skin like that before has thick (4px) arms. It is based on the classic Steve model.
This particular Minecraft I've never seen a skin like that before has the following color palette:
Dark Blue
Torea Bay
Spun Pearl
Blue Haze
Santas Gray